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Aluminum zirconium tetrachlorohydrex gly

Aluminum zirconium tetrachlorohydrex gly suppliers and sourcing guide

Aluminum zirconium tetrachlorohydrex gly is a complex of aluminum zirconium tetrachlorohydrate with glycine, which buffers and stabilizes the zirconium species. It is made by combining aluminum chlorohydrate with a zirconium hydroxychloride solution in the presence of glycine, then spray-drying. Brands buy it mainly as fine powders, standard or activated, for anhydrous sticks and soft solids, and sometimes as solutions.

Also known as
AZG · Aluminum zirconium tetrachlorohydrex glycine · Aluminium zirconium tetrachlorohydrex GLY
Facts checked
November 2026

Forms and grades of aluminum zirconium tetrachlorohydrex gly

Suppliers sell different products under the same name. Specify the one you need.

  • Standard powder

    Spray-dried powder with a defined Al:Zr ratio and particle size for sticks and soft solids.

  • Activated powder

    Grades with a modified polymer size distribution for higher activity; sold with a recommended use-by window.

  • Solutions

    Aqueous or glycol solutions for clear gels and roll-ons.

  • Micronized grades

    Very fine powders for clear or low-residue sticks.

What to check on the COA

Compare each result with your own specification when the lot arrives.

Aluminum, zirconium and chloride
Each element by titration or ICP, with Al:Zr and (Al+Zr):Cl atomic ratios against the compendial ranges.
Glycine content
Glycine by titration or HPLC, which identifies the gly complex.
Anhydrous active
Active content calculated on an anhydrous basis, used for the label percentage.
pH
pH of a 15% w/w solution.
Particle size
Laser diffraction, important for stick texture and visible residue.
Heavy metals
Lead, iron and other metals by ICP; zirconium sources can carry hafnium and uranium-series elements, so ask how they are controlled.

Storage, lots and expiry

Storage and shelf life

Store powders sealed in their original lined containers in a cool, dry place; they are hygroscopic and corrosive to metals. Activated grades lose activity over time, especially in water, so use within the supplier's stated period. Shelf life and retest dates come from the supplier's specification.

Lots and expiry dates

Record Al:Zr ratio, glycine, anhydrous active and particle size for each lot. Note the manufacture date of activated grades and rotate strictly first in, first out.

Regulatory status

Facts from regulators and standards bodies, each linked to its source.

  • 21 CFR 350.10 (2024 edition on govinfo.gov) lists aluminum zirconium tetrachlorohydrex gly up to 20 percent as an OTC antiperspirant active ingredient.

    Source: govinfo.gov (opens in a new tab)
  • Health Canada's Cosmetic Ingredient Hotlist includes aluminum zirconium tetrachlorohydrex GLY in its aluminum zirconium complexes entry, which does not permit them in aerosol deodorants and antiperspirants, bars combining them with other aluminum salts, and sets a 20% limit (anhydrous basis) in other cosmetics.

    Source: canada.ca (opens in a new tab)

This is general information, not regulatory advice. Status differs by country and by how the ingredient is used, so check the rules for your product and market.

Aluminum zirconium tetrachlorohydrex gly suppliers

Manufacturers and distributors whose own websites say they sell it.

  • Elementis

    Manufacturer · London, United Kingdom

    UK specialty chemicals group known for rheology modifiers and antiperspirant actives; its personal care range also lists meadowfoam seed oil and shea butter.

Suppliers are in alphabetical order and none pays to appear. Each claim is checked against the supplier’s own website on the date shown. Ask for the specification sheet and a recent COA before you order, and confirm details with the supplier.

Frequently asked questions

What forms of aluminum zirconium tetrachlorohydrex gly can brands buy?

Common forms include standard powder, activated powder, solutions and micronized grades. Ask each supplier for the specification sheet of the exact grade they quote.

What should the COA for aluminum zirconium tetrachlorohydrex gly include?

Expect aluminum, zirconium and chloride, glycine content, anhydrous active, pH, particle size and heavy metals, each with its method, specification and result for that lot.

How should aluminum zirconium tetrachlorohydrex gly be stored?

Store powders sealed in their original lined containers in a cool, dry place; they are hygroscopic and corrosive to metals. Activated grades lose activity over time, especially in water, so use within the supplier's stated period. Shelf life and retest dates come from the supplier's specification.

What is the regulatory status of aluminum zirconium tetrachlorohydrex gly?

21 CFR 350.10 (2024 edition on govinfo.gov) lists aluminum zirconium tetrachlorohydrex gly up to 20 percent as an OTC antiperspirant active ingredient. Health Canada's Cosmetic Ingredient Hotlist includes aluminum zirconium tetrachlorohydrex GLY in its aluminum zirconium complexes entry, which does not permit them in aerosol deodorants and antiperspirants, bars combining them with other aluminum salts, and sets a 20% limit (anhydrous basis) in other cosmetics.

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